Corrosion Resistance of Zinc Coated Steel in Sea Water Environment

  • Adrian DIACONU "Dunarea de Jos" University of Galati
  • Cătălin SOLOMON "Dunarea de Jos" University of Galati
  • Lidia BENEA "Dunarea de Jos" University of Galati
  • Valentin DUMITRAŞCU "Dunarea de Jos" University of Galati
  • Laurenţiu MARDARE "Dunarea de Jos" University of Galati
Keywords: low alloy steel, galvanizing steel, corrosion behavior, marine environment

Abstract

The life time of metallic materials used in naval transport industry is influenced by their corrosion resistance. For utilization in shipbuilding and offshore construction, metallic materials need to be covered with protective coatings, especially, or different anti-corrosion protection methods need to be used. During the last decades a series of inorganic and organic coatings was developed. Among inorganic coatings, the most used ones are the galvanizing treatments. This paper presents a comparative investigation regarding the corrosion resistance of uncoated low alloy steel and galvanizing steel. Both samples have been subjected to corrosion in sea water harvested from the Black Sea, Mangalia harbor. The electrochemical assays were: open circuit potential (OCP), linear polarization resistance (Rp), potentiodynamic polarization (PD) and cyclic voltammetry. The results obtained by in situ determination were confirmed by optical microscopy. The results revealed an improved corrosion resistance of galvanized steel in natural sea water in comparison with low alloy steel.

Creative Commons License

References

[1]. H. Li, H. Yu, T. Zhou, B. Yin, S. Yin, Y. Zhang, Effect of tin on the corrosion behavior of sea-water corrosion-resisting steel, Materials and Design, 84, p. 1-9, 2015.
[2]. R. E. Melchers, The effect of corrosion on the structural reliability of steel offshore structures, Corrosion Science, 47, p. 2391-2410, 2005.
[3]. D. P. Schmidt, B. A. Shaw, E. Sikora, W. W. Shaw, L. H. Laliberte, Corrosion protection assessment of sacrificial coating systems as a function of exposure time in a marine environment, Progress in Organic Coating, 57, p. 352-364, 2006.
[4]. A. H. Al-Moubaraki, A. Al-Judaibi, M. Asiri, Corrosion of C-steel in Red Sea: Effect of immersion time and inhibitor concentration, Journal of Electrochemical Science, 10, p. 4252-4278, 2015.
[5]. M. A. Arenas, C. Casado, V. Nobel-Pujol, J. de Damborenea, Influence of the conversion coating on the corrosion of galvanized reinforcing steel, Cement & Concrete Composites, 28, p. 267-275, 2006.
[6]. C.-Y. Tsai, J-S. Liu, P.-L. Chen, C.-S. Lin, A roll coating tungstate passivation treatment for hot-dip galvanized sheet steel, Surface & Coatings Technology, 205, p. 5124-5129, 2011.
[7]. B. Ramezanzadeh, M. M. Attar, M. Farzam, Corrosion performance of a hot-dip galvanized steel treated by different kinds of conversion coatings, Surface & Coatings Technology, 205, p. 874-884, 2010.
[8]. D. T. Oloruntoba, O. O. Oluwole, E. O. Oguntade, Comparative study of corrosion behavior of galvanized steel and coated Al 3103 roofing sheets in carbonate and chloride environments, Materials and Design, 30, p. 1371-1376, 2009.
[9]. E. Diler, B. Rouvellou, S. Rioual, B. Lescop, G. Nguyen Vien, D. Thierry, Characterization of corrosion products of Zn and Zn–Mg–Al coated steel in a marine atmosphere, Corrosion Science, 87, p. 111-117, 2014.
[10]. M. Mouanga, M. Puiggali, B. Tribollet, V. Vivier, N. Pébère, O. Devos, Galvanic corrosion between zinc and carbon steel investigated by local electrochemical impedance spectroscopy, Electrochimica Acta, 88, p. 6-14, 2013.
[11]. A. Pritzel dos Santos, S. M. Manhabosco, J. S. Rodrigues, L. F. P. Dick, Comparative study of the corrosion behavior of galvanized, galvannealed and Zn55Al coated interstitial free steels, Surface & Coatings Technology, 279, p. 150-160, 2015.
[12]. Y. Y. Chen, S. C. Chung, H. C. Shih, Studies on the initial stages of zinc atmospheric corrosion in the presence of chloride, Corrosion Science, 48, p. 3547-3564, 2006.
[13]. F. Rosalbino, G. Scavino, D. Macciò, A. Saccone, Influence of the alloying component on the corrosion behavior of zinc in neutral aerated sodium chloride solution, Corrosion Science, 89, p. 286-294, 2014.
[14]. V. Padilla, A. Alfantazi, Corrosion film breakdown of galvanized steel in sulphate–chloride solutions, Construction and Building Materials, 66, p. 447-457, 2014.
[15]. S. S. Xin, M. C. Li, Electrochemical corrosion characteristics of type 316L stainless steel in hot concentrated seawater, Corrosion Science, 81, p. 96-101, 2014.
[16]. K. M. Zohdy, M. M. Sadawy, M. Ghanem, Corrosion behavior of leaded-bronze alloys in sea water, Materials Chemistry and Physics, 147, p. 878-883, 2014.
Published
2015-09-15
How to Cite
1.
DIACONU A, SOLOMON C, BENEA L, DUMITRAŞCU V, MARDARE L. Corrosion Resistance of Zinc Coated Steel in Sea Water Environment. The Annals of “Dunarea de Jos” University of Galati. Fascicle IX, Metallurgy and Materials Science [Internet]. 15Sep.2015 [cited 26Apr.2024];38(3):34-9. Available from: https://www.gup.ugal.ro/ugaljournals/index.php/mms/article/view/1302
Section
Articles

Most read articles by the same author(s)

Obs.: This plugin requires at least one statistics/report plugin to be enabled. If your statistics plugins provide more than one metric then please also select a main metric on the admin's site settings page and/or on the journal manager's settings pages.