Geopolymers Obtained With Red Mud From Alumina Manufacturing
Keywords:
geopolymers, residue, red mud, construction materials
Abstract
Getting reusable aluminosilicate materials, based on the geopolymerization reaction mechanism of some physical and mechanical material particular, has been imposed in the recent years in building materials.
This paper presents the physico-chemical and structural characteristics of the red mud from alumina (Al2O3) manufacturing through the Bayer process, material that can be investigated in order to obtain geopolymeric materials. Geopolymers made from red mud are eco- friendly on the one hand because their synthesis reuses waste from industries as raw materials, and on the other hand, because the conditions through which they can be obtained are more economics and cheap.
References
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[27]. Abhishek H. N., M. U. Aswath - Strength studies of red mud based geopolymers concrete, Int. Juo.of Em. Trends in Eng. and Dev., 6, 2012, p. 10-32.
[28]. Yanju Liu, Ravi Naidu, Hui Ming - Red mud as an amendment for pollutants in solid and liquid phases, Geoderma, 163, 2011, p. 1-12.
[29]. Shaoxin Yang, Yihe Zhanga, Jiemei Yu, Taizhong Huana, Qi Tang, Paul K. Chu, Lei Qi - Multi-functional honeycomb ceramic materials produced from bauxite residues, Materials Design, 59, 2014, p. 333-338.
[30]. Anuj Kumar, Sanjay Kumar - Development of paving blocks from synergistic use of red mud and fly ash using geopolymerization, Construction and Building Materials, 38, 2013, p. 865-871.
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[32]. L. Pérez-Villarejo, F. A. Corpas-Iglesias, S. MartínezMartínez, R. Artiaga, J. Pascual-Cosp - Manufacturing new ceramic materials from clay and red mud derived from the aluminium industry, Construction and Building Materials, 35, 2012, p. 656-665.
[33]. Y. Pontikes, C. Rathossi, P. Nikolopoulos, G. N. Angelopoulos, D. D. Jayaseelan, W. E. Lee - Effect of firing temperature and atmosphere on sintering of ceramics made from Bayer process bauxite residue, Ceramics International, 35, 2009, p. 401-407.
[34]. Nevin Yalçın, Vahdettin Sevinç - Utilization of bauxite waste in ceramic glazes, Ceramics International, 26, 2000, p. 485-493.
[35]. Indrani Ghosh, Saumyen Guha, R. Balasubramaniam, A. V. Ramesh Kumar - Leaching of metals from fresh and sintered red mud, Journal of Hazardous Materials, 185, 2011, p. 662-668.
[36]. Laura Santona, Paola Castaldi, Pietro Melis - Evaluation of the interaction mechanisms between red muds and heavy metals, Journal of Hazardous Materials, B136, 2006, p. 324-329.
[37]. Ramesh Chandra Sahua, Rajkishore Patel, Bankim Chandra Ray - Removal of hydrogen sulfide using red mud at ambient conditions, Fuel Processing Technology, 92, 2011, p. 1587-1592.
[38]. Shaobin Wang, H. M. Ang, M. O. Tadé - Novel applications of red mud as coagulant, adsorbent and catalyst for environmentally benign processes, a review, Chemosphere, 72, 2008, p. 1621-1635.
[39]. Roach G. D., Jamieson, E., Pearson N., Yu A. B. - Effect of particles characteristics on the solids density of Bauer red mud slurries, Light Mnetlas, Anjier, J. L. Ed. TMS, New Orleans, 2001, p. 51-58.
[40]. Grafe M., Power G., Klauber C. - Review of bauxite residue alkalinity and associated chemistry, Light Metals, CSIRO Document DMR-3610, May 2009.
[41]. Florea Oprea, I. Constantin, R. Roman, D. Taloi - Teoria proceselor metalurgice, Editura Didactică și Pedagogică București, 1978, p. 372.
[2]. I. García-Lodeiro, A. Palomo, A. Fernández-Jiménez - Alkali–aggregate reaction in activated fly ash systems, Cem. Concr. Res., 37 (2), 2007, p. 175-183.
[3]. J. M. Miranda, A. Fernández-Jiménez, J. A. González, A. Palomo - Corrosion resistance in activated fly ash mortars, Cem. Concr. Res., 35 (6), 2005, p. 1210-1217.
[4]. W. Mozgawa, J. Deja - Spectroscopic studies of alkaline activated slag geopolymers, Journal of Molecular Structure, 924–926, 2009, p.434-441.
[5]. M. Komljenovic´, Z. Bašcarevic´, N. Marjanovic´, V. Nikolic - External sulfate attack on alkali-activated slag, Construction and Building Materials, 49, 2013, p. 31-39.
[6]. A. Natali Murri, W. D. A. Rickard, M. C. Bignozzi, A. van Riessen - High temperature behaviour of ambient cured alkaliactivated materials based on ladle slag, Cement and Concrete Research, 43, 2013, p. 51-61.
[7]. Davidovits J. - Properties of geopolymer cements, In: First international conference on alkaline cements and concretes, 1994.
[8]. Zhang G. P., He J. A., Gambrell R. P. - Synthesis, characterization, and mechanical properties of red mud-based geopolymers, Transp Res. Rec., 2167, 2010, p. 1-9.
[9]. Xiaoming Liu, Na Zhang, Henghu Sun, Jixiu Zhang, Longtu Li - Structural investigation relating to the cementitious activity of bauxite residue - Red mud, Cement and Concrete Research, 41, 2011, p. 847-853.
[10]. Arie van Riessen, Evan Jamieson, Catherine S. Kealley, Robert D. Hart, Ross P. Williams - Bayer-geopolymers: An exploration of synergy between the alumina and geopolymer industries, Cement & Concrete Composites, 41, 2013, p. 29-33.
[11]. Saeed Ahmari, Xin Ren, Vahab Toufigh, Lianyang Zhang - Production of geopolymeric binder from blended waste concrete powder and fly ash, Construction and Building Materials, 35, 2012, p. 718-729.
[12]. L. Reig, M. M. Tashima, M. V. Borrachero, J. Monzó, C. R. Cheeseman, J. Payá - Properties and microstructure of alkaliactivated red clay brick waste, Construction and Building Materials, 43, 2013, p. 98-106.
[13]. Ubolluk Rattanasak, Prinya Chindaprasirt - Influence of NaOH solution on the synthesis of fly ash geopolymer, Minerals Engineering, 22, 2009, p. 1073-1078.
[14]. R. E. Lyon, P. N. Balaguru, A. Foden, U. Sorathia, J. Davidovits, M. Davidovics - Fire-resistant aluminosilicate composites, Fire Mater., 21 (2), 1997, p. 67-73.
[15]. Shaotao Cao, Haijun Ma, Yi Zhang, Xiaofan Chen, Yifei Zhang, Yi Zhang - The phase transition in Bayer red mud from China in high caustic sodium aluminate solutions, Hydrometallurgy, 140, 2013, p. 111-119.
[16]. Vladimır Zivica - Effects of type and dosage of alkaline activator and temperature on the properties of alkali-activated slag mixtures, Construction and Building Materials, 21, 2007, p. 1463-1469.
[17]. Benny Joseph, George Mathew - Influence of aggregate content on the behavior of fly ash based geopolymer concrete, Scientia Iranica, 19, 2012, p. 1188-1194.
[18]. M. Gräfe, G. Power, C. Klauber - Bauxite residue issues: III. Alkalinity and associated chemistry, Hydrometallurgy, 108, 2011, p. 60-79.
[19]. ***, http://en.wikipedia.org/wiki/Bayer_process. [20]. P. E. Tsakiridis, S. Agatzini-Leonardou, P. Oustadakis - Red mud addition in the raw meal for the production of Portland cement clinker, Journal of Hazardous Materials, 116, 2004, p. 103-110.
[21]. Maneesh Singh, S. N. Upadhayay, P. M. Prasad - Preparation of iron rich cements using red mud, Cement and Concrete Research, 27, 1997, p. 1037-1046.
[22]. Yiannis Pontikes, Ruben Snellings - Handbook of Recycling, 2014, p. 219-229.
[23]. L. Senff, R. C. E. Modolo, A. Santos Silva, V. M. Ferreira, D. Hotza, J. A. Labrinchae - Influence of red mud addition on rheological behavior and hardened properties of mortars, Construction and Building Materials, 65, 2014, p. 84-91.
[24]. D. V. Ribeiro, J. A. Labrincha, M. R. Morelli - Effect of the addition of red mud on the corrosion parameters of reinforced concrete, Cement and Concrete Research, 42, 2012, p. 124-133.
[25]. D. V. Ribeiro, J. A. Labrincha, M. R. Morelli - Effect of the addition of red mud on the corrosion parameters of reinforced concrete, Cement and Concrete Research, 42, 2012, p. 124-133.
[26]. W. Hajjajia, S. Andrejkovičová, C. Zanelli, M. Alshaaer, M. Dondi, J. A. Labrincha, F. Rocha - Composition and technological properties of geopolymers based on metakaolin and red mud, Materials Design, 52, 2013, p. 648-654.
[27]. Abhishek H. N., M. U. Aswath - Strength studies of red mud based geopolymers concrete, Int. Juo.of Em. Trends in Eng. and Dev., 6, 2012, p. 10-32.
[28]. Yanju Liu, Ravi Naidu, Hui Ming - Red mud as an amendment for pollutants in solid and liquid phases, Geoderma, 163, 2011, p. 1-12.
[29]. Shaoxin Yang, Yihe Zhanga, Jiemei Yu, Taizhong Huana, Qi Tang, Paul K. Chu, Lei Qi - Multi-functional honeycomb ceramic materials produced from bauxite residues, Materials Design, 59, 2014, p. 333-338.
[30]. Anuj Kumar, Sanjay Kumar - Development of paving blocks from synergistic use of red mud and fly ash using geopolymerization, Construction and Building Materials, 38, 2013, p. 865-871.
[31]. Jaana Sorvari, Margareta Wahlstrom - Handbook of Recycling, 2014, p. 231-253.
[32]. L. Pérez-Villarejo, F. A. Corpas-Iglesias, S. MartínezMartínez, R. Artiaga, J. Pascual-Cosp - Manufacturing new ceramic materials from clay and red mud derived from the aluminium industry, Construction and Building Materials, 35, 2012, p. 656-665.
[33]. Y. Pontikes, C. Rathossi, P. Nikolopoulos, G. N. Angelopoulos, D. D. Jayaseelan, W. E. Lee - Effect of firing temperature and atmosphere on sintering of ceramics made from Bayer process bauxite residue, Ceramics International, 35, 2009, p. 401-407.
[34]. Nevin Yalçın, Vahdettin Sevinç - Utilization of bauxite waste in ceramic glazes, Ceramics International, 26, 2000, p. 485-493.
[35]. Indrani Ghosh, Saumyen Guha, R. Balasubramaniam, A. V. Ramesh Kumar - Leaching of metals from fresh and sintered red mud, Journal of Hazardous Materials, 185, 2011, p. 662-668.
[36]. Laura Santona, Paola Castaldi, Pietro Melis - Evaluation of the interaction mechanisms between red muds and heavy metals, Journal of Hazardous Materials, B136, 2006, p. 324-329.
[37]. Ramesh Chandra Sahua, Rajkishore Patel, Bankim Chandra Ray - Removal of hydrogen sulfide using red mud at ambient conditions, Fuel Processing Technology, 92, 2011, p. 1587-1592.
[38]. Shaobin Wang, H. M. Ang, M. O. Tadé - Novel applications of red mud as coagulant, adsorbent and catalyst for environmentally benign processes, a review, Chemosphere, 72, 2008, p. 1621-1635.
[39]. Roach G. D., Jamieson, E., Pearson N., Yu A. B. - Effect of particles characteristics on the solids density of Bauer red mud slurries, Light Mnetlas, Anjier, J. L. Ed. TMS, New Orleans, 2001, p. 51-58.
[40]. Grafe M., Power G., Klauber C. - Review of bauxite residue alkalinity and associated chemistry, Light Metals, CSIRO Document DMR-3610, May 2009.
[41]. Florea Oprea, I. Constantin, R. Roman, D. Taloi - Teoria proceselor metalurgice, Editura Didactică și Pedagogică București, 1978, p. 372.
Published
2014-06-15
How to Cite
1.
SPĂTARU I, VLAD M. Geopolymers Obtained With Red Mud From Alumina Manufacturing. The Annals of “Dunarea de Jos” University of Galati. Fascicle IX, Metallurgy and Materials Science [Internet]. 15Jun.2014 [cited 29Apr.2024];37(2):45-3. Available from: https://www.gup.ugal.ro/ugaljournals/index.php/mms/article/view/2500
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