Influence of Micro Glass Beads Added in a PBT Matrix on the Mechanical Properties of Composites
Keywords:
PBT, glass beads, composite, elasticity modulus, stress at break, elongation at break, energy at break
Abstract
This paper presents the influence of adding materials (micros glass spheres) in a matrix of PBT on several mechanical properties: elasticity modulus, stress at break , elongation at break, energy at break.
The mechanical properties of these composites depend on the glass beads concentration. The additivation of polybuthylen therephtalate with glass beads increases the values of the elasticity modulus, but reduces quite drastically the elongation at break. Using the SEM investigation, the authors pointed out the particular aspects of fracture surfaces: a ductile process at sample margins and a brittle one in the middle of the composite.
References
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[24]. Vincent L., Connolly S. N., Dolan F., Willcocks P.H., Pendlebury R. - Determination and Comparison of the Plane Stress Essential Work of Fracture of Three Polyesters PET, PPT and PBT, Journal of Thermal Analysis and Calorimetry, Vol. 86, 1, pp. 147-154, (2006).
[25]. Yang W., Liu Z.-Y., Shan G.-F., Li Z.-M., Xie B.-H., Yang M.-B. - Study on the melt flow behavior of glass bead filled polypropylene, Polymer Testing, 24, pp. 490-497, (2005).
[26]. *** DuPont Engineering Polymers. Blow Moulding of Technical Components, Available from: http://www2.dupont.com/Plastics/en_US/assets/downloads/processing/BM_PM_e.pdf Accessed: 2012-01-12.
[27]. *** DuPont. Crastin® PBT. thermoplastic polyester resin Crastin® 6130 NC010, Available from: http://plastics.dupont.com/plastics/dsheets/crastin/CRASTIN6130NC010.pdf Accessed: 2012-01-12.
[28]. *** Polybutylene Terephthalate (PBT), on-line: http://www.rtpcompany.com/info/guide/descriptions/1000.htmAccessed: 2012-01-23.
[29]. *** SR EN ISO 527-2:2000 Materiale plastice. Determinarea proprietăţilor de tracţiune. Partea 2: Condiţii de încercare a materialelor plastice pentru injecţie şi extrudare.
[2]. Akiyama, M., Yamaguchi, T., Matsumoto, K., Hokkirigawa, K. - Polymer Composites Filled with RB Ceramics Particles as Low Friction and High Wear Resistant Filler, Tribology online, Vol. 5, No. 1, January, pp. 19-25, (2010).
[3]. Arencon D., Velasco J.I., Realinho V., Antunes M., Maspoch M.L. - Essential work of fracture analysis of glass microsphere-filled polypropylene and polypropylene/poly (ethylene terephthalate-co-isophthalate) blend-matrix composites, Polymer Testing, 26, pp. 761-769, (2007).
[4]. Bai S.-L. - The role of the interfacial strength in glass bead filled HDPE, Journal of Materials Science Letters, 19, pp. 1587-158, (2000).
[5]. Banik K., Mennig G. - Influence of the Injection Molding Process on the Creep Behavior of Semicrystalline PBT During Aging Below its Glass Transition Temperature, Mechanics of Time-Dependent Materials, 9, pp. 247-257, 2006.
[6]. Bessmertnyi V.S., Krokhin V.P., Lyashko A.A., Drizhd N.A., Shekhovtsova Zh. E. - Production of Glass Microspheres Using the Plasma-Spraying Method, Glass and Ceramics, vol. 58, nos.7-8, (2001).
[7]. Brandrup, J., Immergut, E.H. & Grulke E.A. - Polymer Handbook, 4th Edition, Wiley-Interscience, England, (2003).
[8]. Brown, R., - Handbook of Polymer Testing - Short-Term Mechanical Tests, Rapra Technology, U.K., (2002).
[9]. Brydson, J.A. - Plastics Materials, 7th Edition, ButterworthHeinemann, Oxford, (1999).
[10]. Bula K., Jesionowski T., Krysztafkiewicz A., Janik J. - The effect of filler surface modification and processing conditions on distribution behaviour of silica nanofillers in polyesters, Colloid Polym Sci, 285, pp.1267-1273, (2007).
[11]. Crowson R.J., Arridge R. G. C. - The elastic properties in bulk and shear of a glass bead-reinforced epoxy resin composite, Journal of Materials Science, 12, pp. 2154-2164, (1977).
[12]. Dekkers M. E. J., Heikens D. - Crazing and shear deformation in glass bead-filled glassy polymers, Journal of Materials Science, 20, pp. 3873-3880, (1985).
[13]. Dekkers M. E. J., Heikens D. - Shear band formation in polycarbonate-glass bead composites, Journal of Materials Science, 19, pp. 3271-3275, (1984).
[14]. Deleanu L., Andrei G., Maftei L., Georgescu C., Cantaragiu A. - Wear maps for a class of composites with polyamide matrix and micro glass spheres, Journal of the Balkan Tribological Association, vol. 17, no 3, pp. 371-379, (2011).
[15]. Deshmukh G.S., Peshwe D.R., Pathak S.U., Ekhe J.D. - A study on effect of mineral additions on the mechanical, thermal, and structural properties of poly (butylene terephthalate) (PBT) composites, J Polym Res, 18, pp. 1081-1090, (2011).
[16]. Deshmukh G.S., Peshwe D.R., Pathak S.U., Ekhe J.D. - Evaluation of mechanical and thermal properties of Poly (butylene terephthalate) (PBT) composites reinforced with wollastonite, Transactions of The Indian Institute of Metals, vol. 64, issues 1 & 2, February-April, pp. 127-132, (2011).
[17]. Kolesov Yu. I., Kudryavtsev M. Yu., Mikhailenko N. Yu. - Science for Glass Production Types and Compositions of Glass for Production of Continuous Glass Fiber (Review), Glass and Ceramics, vol. 58, nos. 5-6, (2001).
[18]. Lahiri J., Paul A. - Effect of interface on the mechanical behaviour of glass bead-filled PVC, Journal of Materials Science, 20, pp. 2253-2259, (1985).
[19]. Le Blanc J. - Filled Polymers. Science and Industrial Applications, Taylot & Francis Group, (2010).
[20]. Maftei L. - Contribuţii la studiul comportării tribologice a compozitelor cu poliamidă şi microsfere de sticlă, PhD, "Dunarea de Jos" University, Galati, (2010).
[21]. Meddad A., Fisa B. - Filler–matrix debonding in glass beadfilled polystyrene, Journal of Materials Science, 32 pp. 1177-1185, (1997).
[22]. Sánchez-Soto M., Gordillo A., Maspoch M. LL., Velasco J.I., Santana O.O., Martínez A.B. - Glass bead filled polystyrene composites: morphology and fracture, Polymer Bulletin, 47, 587-594, (2002).
[23]. Tsui C.P., Chen D.Z., Tang C.Y., Uskokovic P.S., Fan J.P., Xie X.L. - Prediction for debonding damage process and effective elastic properties of glass-bead-filled modified polyphenylene oxide, Composites Science and Technology, 66, pp. 1521-1531, (2006).
[24]. Vincent L., Connolly S. N., Dolan F., Willcocks P.H., Pendlebury R. - Determination and Comparison of the Plane Stress Essential Work of Fracture of Three Polyesters PET, PPT and PBT, Journal of Thermal Analysis and Calorimetry, Vol. 86, 1, pp. 147-154, (2006).
[25]. Yang W., Liu Z.-Y., Shan G.-F., Li Z.-M., Xie B.-H., Yang M.-B. - Study on the melt flow behavior of glass bead filled polypropylene, Polymer Testing, 24, pp. 490-497, (2005).
[26]. *** DuPont Engineering Polymers. Blow Moulding of Technical Components, Available from: http://www2.dupont.com/Plastics/en_US/assets/downloads/processing/BM_PM_e.pdf Accessed: 2012-01-12.
[27]. *** DuPont. Crastin® PBT. thermoplastic polyester resin Crastin® 6130 NC010, Available from: http://plastics.dupont.com/plastics/dsheets/crastin/CRASTIN6130NC010.pdf Accessed: 2012-01-12.
[28]. *** Polybutylene Terephthalate (PBT), on-line: http://www.rtpcompany.com/info/guide/descriptions/1000.htmAccessed: 2012-01-23.
[29]. *** SR EN ISO 527-2:2000 Materiale plastice. Determinarea proprietăţilor de tracţiune. Partea 2: Condiţii de încercare a materialelor plastice pentru injecţie şi extrudare.
Published
2012-06-15
How to Cite
1.
BOTAN M, GEORGESCU C, DELEANU L. Influence of Micro Glass Beads Added in a PBT Matrix on the Mechanical Properties of Composites. The Annals of “Dunarea de Jos” University of Galati. Fascicle IX, Metallurgy and Materials Science [Internet]. 15Jun.2012 [cited 29Apr.2024];35(2):64-1. Available from: https://www.gup.ugal.ro/ugaljournals/index.php/mms/article/view/2895
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