Studies Regarding Nickel Electrodeposition from Watts Bath with Addition of Polyvinylpyrrolidone and Sodium Saccharine

  • Violeta VASILACHE Stefan cel Mare University of Suceava, Romania
  • Sonia GUTT Stefan cel Mare University of Suceava, Romania
  • Georg GUTT Stefan cel Mare University of Suceava, Romania
  • Ion SANDU "Al. I. Cuza" University of Iasi, Romania
  • Traian VASILACHE S.C. Daflog S.R.L., Mediaş, Romania
  • Victor Andrei SANDU "Gheorghe Asachi" Technical University of Iasi, Romania
Keywords: nickel electrodeposition, Watts bath, polyvinylpyrrolidone, sodium saccharine, SEM-EDX technique

Abstract

This paper is based on some studies about the influence of polyvinylpyrrolidone (PVP) and sodium saccharine as far as concern their influence on the nickel electroplating processes from Watts bath. PVP is a wetting agent which improves the quality of deposited layers. Sodium saccharine is a leveling agent which improves adherence and brightness of the deposited layers. PVP actions through the inhibition of adsorption of (NiOH)+ species on the cathode surface. Sodium saccharine controls crystals growth on the electro-crystallization process. Our results are able to promote using of these additives for future commercial applications. SEM-EDX techniques and optical microscopy were used with the aim to emphasize the uniformity, the continuality and the micro-structural granularity of the electrodeposited layers,, correlated with chemical composition and metallic brightness, through absorption spectroscopy.

Creative Commons License

References

[1]. Bard, A., J. - Electrochemical Methods. Fundamentals and Applications, John Wiley and Sons, New-York, 2001.
[2]. Di Bari, G. - Electrodeposition of Nickel, Modern Electroplating, Fourth Edition, John Wiley and Sons, Inc. NewYork, 2000.
[3]. Cui, C., Q., Lee, J., K. - Electrochemistry Acta 40 (1995) 1653.
[4]. Firoiu, C. - Tehnologia proceselor electrochimice, Editura Didactică şi Pedagogică, Bucureşti, 1983.
[5]. Grünwald, E. - Tehnologii moderne de galvanizare în industria electronică şi electrotehnică, Editura Casa Cărţii de Ştiinţă, Cluj- Napoca, 1995.
[6]. Grünwald, E., Mureşan, L., Vermeşan, G., Vermeşan, H., Culiuc, A. - Tratat de galvanotehnică, Editura Casa Cărţii de Ştiinţă, Cluj- Napoca, 2005.
[7]. Holm, M., O, Kofe, T. - Journal of Applied Electrochemistry, 30 (2000) 1125-1132.
[8]. Mohanty, U., S., Tripathy, B., C., Das, S., C., Mistra, V., N. - Metallurgical and Materials Transactions B, Vol.36b (2005) 737.
[9]. Mitoşeriu, O., Iticescu, C., Cârâc, G., Revista de Chimie, Bucureşti, 55, nr. 7, (2004) 525-529.
[10] R. Valotkiene, K. Leinartas, D. Virbalyte, E. Juzeliunas - Chemija (Vilnius), 4, T12, 236 (2001).
[11]. Paunovič, M., Schlesinger, M., and Weil, R. - Fundamental Considerations, Modern Electroplating, Fourth Edition, John Wiley and Sons, Inc. New-York, 2000.
[12]. Tripathy, B., C., Singh, P., Muir, D., M., Das, S., C. - Journal of Applied Electrochemistry 31: 301-305, 2001.
[13]. Vasilache, V., Gutt, Gh., Vasilache, T. - Electrochemical researches about influence of the additives of Watts s solutions on throwing power and brightness, Revista de Chimie, Bucureşti, 59 (2008).
[14]. Vasilache, V. - Contribuţii teoretice şi practice la optimizarea proceselor de depunere galvanică folosite în industria constructoare de maşini, Referatul 3 în cadrul stagiului de pregătire pentru doctorat, Suceava, 2008.
[15]. Vasilache, V. - Contribuţii la optimizarea proceselor de depunere galvanică a nichelului şi a aliajelor de nichel folosite în construcţia de maşini, Teza de doctorat, Suceava, 2007.
Published
2009-05-15
How to Cite
1.
VASILACHE V, GUTT S, GUTT G, SANDU I, VASILACHE T, SANDU VA. Studies Regarding Nickel Electrodeposition from Watts Bath with Addition of Polyvinylpyrrolidone and Sodium Saccharine. The Annals of “Dunarea de Jos” University of Galati. Fascicle IX, Metallurgy and Materials Science [Internet]. 15May2009 [cited 29Apr.2024];32(1):95-9. Available from: https://www.gup.ugal.ro/ugaljournals/index.php/mms/article/view/3075
Section
Articles

Most read articles by the same author(s)

Obs.: This plugin requires at least one statistics/report plugin to be enabled. If your statistics plugins provide more than one metric then please also select a main metric on the admin's site settings page and/or on the journal manager's settings pages.